Plug and abandonment of oil and gas wells: Different materials

By Miguel Diaz - December 21, 2017

Plug and abandonment of oil and gas wells_Different materials

Cement IS NOT the only material for well abandonment. In this article, we will address the doubts around the material that could be placed in the hole as a barrier for plug and abandonment, and whether those materials differ depending on time span defined for the barriers life. So now, let's dig further into the matter.

The Gulf of Mexico (GoM) and the North Sea are two relevant places regarding the availability of detailed and comprehensive legislation that addresses the well abandonment process.

Also refer to the UK offshore oil and gas organization (UKOG) ( series of three documents on well abandonment practices. They include a "Guideline on qualification of materials for the abandonment of wells."

It was issued in 2012 and reviewed three years after with contributions from experts from Shell, the University of Dundee, ConocoPhillips, SINTEF, TNO, Schlumberger, BP, Chevron, ExxonMobil, Los Alamos National Lab, Sandaband, Halliburton, Baker BJ Services, TOTAL, Raw water and Wellcem.

Temporal or permanent it is all the same

When we place barriers in the well to isolate formations from each other and the surface with no intention to ever re-enter the abandoned part of the wellbore, the abandonment is considered a permanent one. Where there is an intention to re-enter, we call it temporary abandonment (typically a matter of months).

Besides the timeline of the application, the only other difference between permanent and temporary abandonment is that a temporary barrier is not required to extend across the full section of the well and include all annuli.

Other than that, a temporary barrier must fulfil some functions, which we discuss below, and they do not differ from those of permanent barriers, except possibly for a relaxed timescale of required durability.



Again, the UKOG guideline defines the requirements for a well abandonment barrier to be successful, those are:


A leak is a breach of integrity which passes entirely through the barrier. Such a gap can take the form of a crack or channel and may be present from the start of placement or develop over a long or short period. Failure can occur due to debonding, dissolution or cracking.

The primary function of a permanent barrier is to provide a seal against leaks. But, the curious thing is that the guideline considers inevitable that fluid within the well will ultimately migrate past a barrier, albeit at a low rate.

Thus, appropriate barriers are those through which the rate of permeation is acceptably low. The approach taken is to require that the barrier permits leakage of fluids at the same or a lower rate than the caprock.

The permeability of caprock is typically within the range of 0.001-1 micro Darcy. But from historical industry experience, barriers of 30m (100 ft) of “good” cement (usually with a permeability of 10 micro Darcy) are performing to a level satisfying the oil and gas industry.

Click picture for larger version

Skjermbilde 2017-10-23 kl. 09.13.39.pngFigure 1: Barrier Failure modes (Source, Oil & Gas UK)

A maximum permeability of 10 micro Darcy has then become the acceptance criteria for the qualification of a cement barrier of the sort discussed above. If permeability is lower, a shorter barrier may be installed. Longer barriers could be used for more permeable materials.


Once placed, the barrier should not move, either along the wellbore or in a lateral direction. For instance, the barriers should not be pushed upwards by pressure developing below. The barrier materials are required to remain attached to interfaces to where it was installed.

Materials used for P&A should pass shear bond stress tests demonstrating what delta pressures are needed to extrude the materials out of a cylindrical cell that mimics a cased well.


The permanent barrier material should be easily placed in a wellbore at the desired depth and perform as required. Therefore, it should have appropriate properties that allow it to displace the existing fluids and form a continuous sealing medium, even when considering its inevitable contamination.

Where a barrier material undergoes a transformation from liquid to a solid, this period of change must be sufficiently short to prevent an escape of fluid and unacceptable disruption of the barrier.

Verification of the barrier placement must be possible even in deviated wells.

Read more: Lab tests to review when designing a “gas-tight” cement slurry


The barrier material should not degrade such that its sealing capabilities or position are compromised. It should be able to withstand wellbore changing conditions for ages.

5.Removal and reparability

Being removable is a fundamental element if the abandonment was a temporal one. The barrier should be easy to remove with existing conventional industry methods (drill bits, mills, acid, etc.). Also, if a leak through a barrier would develop, there should be a method to remove/repair it to regain integrity.

6.Operating conditions

After placement and activation, the permanent barrier material will have to withstand external loadings that could vary with time, among those are:

  1. Reservoir pressure
    This could fluctuate downwards or upwards. The former as result of the normal drainage of formation fluids, and the latest as result of the re-charging of the depleted reservoir due to connectivity with another formation, or re-pressurization through injection of fluids, gas injected for storage, etc. During abandonment, rapid decompression may damage specific barrier materials.
  2. Temperature.
    Follows geological patterns when left undisturbed. Temperature could change during the production life of a field as a result of fluid injection, gas storage, etc.
  3. Mechanical stresses.
    Naturally occurring subsidence or tectonic forces may act on a permanent barrier. Additionally, changes in temperature will cause expansion and contraction. These stresses could be enough for the barrier to crack and create leak paths.
  4. Chemicals
    Barrier materials may be exposed to substances such as hydrocarbons, CO2, H2S, brine, etc., all of which are severely corrosive and could eat through metals and isolation barriers. For some materials, the presence of water or micro-organism with the ability to digest barrier materials (i.e. Bacteria) will have to be considered, evaluated and counter-acted.


Having read these expected requirements for a material to be considered a qualified abandonment barrier;

- How much do you think cement embraces those aspects mentioned?

- Do you think there is anything else out there that qualifies for this?

Cement is currently used in wells as the prime material for abandonment purposes because it is found to have similar properties to the rock that it is replacing. However, given its operational limitations, alternative materials, which offer significant advantages over cement, are being proposed and developed by the industry.

These substances, however, still don't replace cement. That's because - when compared with cement that has been used for hundred years or so - uncertainty with regards to long-term integrity of the alternative materials acts as disincentive for their use.

The legislation, as reviewed last week, also play a role in the incentive to use cement for P&As; some countries refer only to cement as abandonment material in their legislation, while some others ask for an abandonment material to be “equivalent to cement."

Click table for larger version

Skjermbilde 2017-10-23 kl. 09.21.54.png

Figure 2: Material types for permanent barriers (source, Oil & Gas UK)

The UKOG guideline for qualification of materials then defines (see table above) a list of materials that offer characteristics that meet all the functional requirements for permanent barriers that we reviewed above. I will give you a summary:

  • Very low permeability – to prevent flow of fluids through the bulk material
  • Provide an interface seal; the material seals along the interface with adjacent materials such as steel pipe or rock; risks of shrinkage and de-bonding are considered.
  • The barrier material must remain at the intended position and depth in the well.
  • Long-term integrity; the material doesn’t deteriorate over time; risks of cracks and de-bonding over time are considered.
  • Resistance to downhole fluids (i.e. CO2, H2S, hydrocarbons, brine) at foreseeable pressures and temperatures.
  • Mechanical properties suitable to accommodate loads at foreseeable temperatures and pressures.


From the list, the two that have made more advances in recent years are Thermo-setting polymers (Group C) and the modified in-situ materials (group J).

This last case particularly refers to "Melting the cap rock," which consists of using a thermite plug to seal off the well by melting both the well components and the rock formation around them to recreate the cap rock.

This method was trialed last year by Centrica in Canada claiming it could potentially reduce well P&A costs by more than 50%. 


Figure 3: Throughout the transition from liquid to solid, the resin continually transmits hydrostatic pressure to the formation, i.e., there is no "Transition time" as with Portland cement.

The Thermo-setting slurries have been around for a slightly longer time. Once introduced, it was evident that resins have a lot to offer.

Using the "requirements for permanent barriers" as a checklist - and with a comparison against cement in mind - the resins have:

  • lower permeability
  • superior adhesion and less shrinkage
  • low yield point and low viscosity in the unset state
  • flexibility and toughness after setting
  • resistance to many caustic and corrosive chemicals (i.e. CO2, H2S, hydrocarbons, brine) at high pressures and temperature conditions
  • it withstand impurities in the wellbore without significant degradation in performance
  • it is compatible with most drilling fluids
  • can be mixed and pumped through conventional equipment

In 2012, the first couple of cases of bull-heading abandonment were documented in the Gulf of Mexico (Charpiot & Jones, Offshore Magazin, May 2013). In the first one, a weighted resin with low-viscosity was used to abandon a well due to its ability to be placed with minimal injectivity and yet provide high-compressive strength after setting. The well represented a closed system because the platform sheared away during a hurricane.

The same year in another Gulf of Mexico-well, bubbles were coming from the annulus after an initial cut on the casing. In this case, the resin was used in a squeeze application, stopping the annular leak. Subsequently, a 50-ft (15-m) resin plug was set. The resin had a low yield point, and due to its ability to be formulated free of solids, it penetrated small cracks and micro-annuli without the risk of particle bridging. 

In March 2016, the Gulf of Mexico’s first lower abandonment using resin took place. Because there was a downhole obstruction, the operator of this particular field determined that it could not reliably carry out a lower temporary abandonment with cement. Cement could have separated or dehydrated under tight spaces in the restricted flow paths, whereas resin would have had no such issues. In this particular case, dual-coiled tubing risers were used to deliver fluids from the waterline down to the mudline. 

In June 2017, another interesting P&A operation was carried out in the Middle East, with a thermos-setting polyester resin. The well involved was drilled in November 1979 and in April 2017 it developed 1,100 psi of sustain casing pressure in the 4½” x 9⅝” tubing-casing annulus (TCA). At the same time, the H2S Rupture Exposure Radius (RER) for the well was reported as 63 meters to the half "Low flammable limit” (LFL) and 1049 meters to the 30 ppm concentration threshold.

As per client definition, a well is located in a populated area “if the population exceeds 20 persons residing, working, or otherwise located within the 30 ppm rupture exposure radius (RER)”. In this case, significant civilian’s structures existed within that radius; a Highway at 524 meters and a hospital at 786 meters, for instance.

The ultimate goal of the workover operation was to re-complete the well running a 4-1/2” liner inside the 7-inch liner (covering the existing perforations). But before a rig could move in and remove the existing completion, the integrity of the well have to be re-gained taking into consideration the limitations given by the pressurized annulus, H2S levels present on the formation and the well surface location.

The operation was set to be done with a 1-1/2” Coiled tubing giving the ID restrictions of the 2-7/8” completion tubing in the well. Resin was chosen as the barrier. The low viscosity allowed lower pumping pressures while placement, and the solid free nature enabled maximum penetration during the squeeze operation. (1,000 – 1,200 psi pressure limitation set for the job due to casing conditions).

Nine and a half barrels of an 88 pcf thermo-activated polymer resin was spotted without inconvenience.

The resin plug was then pressure tested and milled allowing the well to be circulated with full returns and a new 4-1/2” liner cemented in place.

The job was a success proving resins can be used for P&A and, also, it can be placed safely with one of the smaller available coiled tubing pipes in the market.


Read also: "Collapse in the tubing and casing" and "Plugging a well with no mechanical integrity".

Coming up

With alternatives to cement, materials for P&A now give you more options. You can choose the material that targets your specific goal and fulfills the requirements of the operation.

The next part of this article series will cover abandonment techniques (placement methods etc., including some of the new technologies that are out there already).

So, stick around!


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